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51.
Masaaki Kijima 《商业与工业应用随机模型》2021,37(1):17-20
In this note, some point of views on virtual ages are presented in terms of the discussion paper written by Finkelstein and Cha, which include generalized stochastic order‐based virtual ages, system‐level virtual ages, virtual ages in Weibull distribution and repair degrees with virtual ages. Finally, some possible future researches on virtual ages are described. 相似文献
52.
单碱基错配的识别和稳定性差异在核酸多态性研究中至关重要。在同一电化学传感器平台上,采用电化学发光(ECL)和电化学阻抗(EIS)2种技术,协同研究DNA链中不同类型和不同位点的单碱基错配识别和稳定性差异。电极表面具有茎环构象的探针DNA与完全互补DNA、不同类型或不同位点单碱基错配DNA杂交前后的ECL和EIS信号强度变化有显著差异。信号强度变化可揭示单碱基错配识别的稳定性。结果表明,DNA链中心位点的C-A单碱基错配稳定性低于链两端的,靠近键合电极表面双链链端的C-A单碱基错配稳定性低于非键合电极表面双链链端的,同一中心位点C-X碱基对的稳定性顺序为C-G?C-T>C-A≥C-C。研究结果可为核酸多态性研究提供参考。 相似文献
53.
为寻求新型热障涂层用陶瓷材料,本文采用高温固相烧结法制备了(Sm0.5Gd0.2Nd0.3)2(Hf0.3Ce0.7)2O7复合氧化物。利用XRD分析了其晶体结构,SEM分析其显微组织,膨胀仪测试其热膨胀性能,激光热导仪测试其热扩散系数。结果表明,成功制备了具有单一萤石晶体结构的(Sm0.5Gd0.2Nd0.3)2(Hf0.3Ce0.7)2O7复合氧化物。其显微组织结构致密,晶界清晰无其他相存在。由于复杂的元素组成和较大的原子量,其热导率明显低于7YSZ和Sm2Ce2O7。其较低的热膨胀系数则归因于B位离子较小的离子半径,但其热膨胀系数依然满足热障涂层的要求。 相似文献
54.
55.
In this paper, a quantum cascade laser (QCL) design is proposed based on GaAs/AlGaAs material system, which simultaneously operates at three widely separated wavelengths ( and ). In the design, all the wavelength radiations are achieved by the engineering of the electronic spectrum via the quantum-well widths and the applied electric field in a single active region within a same waveguide. The mid-infrared (mid-IR) wavelengths are obtained by adoption a dual-upper-state active region, and the proposed design aims to use both the mid-IR radiations as the coherent deriving fields to populate the upper THz lasing state to aid the THz-laser population inversion via optical pumping instead of direct electrical injection. A detailed analysis of electronic transport in the structure is carried out using a multi-level rate-equation model. The results show that the proposed structure offers an alternative approach to room temperature THz generation in QCLs. 相似文献
56.
YU Yue XI Zhixiang ZHOU Bingjie JIANG Binbo LIAO Zuwei YANG Yao WANG Jingdai HUANG Zhengliang SUN Jingyuan YANG Yongrong 《高等学校化学研究》2022,38(4):1012-1017
Acidity plays a vital role in methane conversion by co-feeding method, which is one of the best strategies to improve the utilization and gentle the reaction conditions of methane. In this work, Zn, Ni, Mo, La, Ga, Fe and Co-impregnated ZSM-5 zeolites have been prepared with the same substitutions to variate the acidities and tested in co-aromatization of methanol with methane. It is demonstrated that the new medium-strong acid sites formed by metal and strong acid sites are the key role to activate methane in co-reaction. Zn-modified ZSM-5 catalyst is preferred to exhibit the best methane conversion of 12%, whose aromatic selectivity increases from 27.2% to 52.2% compared with that of HZSM-5. Besides, the addition of methane further improves the production of high-valued aromatics compared with methanol to aromatics (MTA) reaction. 相似文献
57.
Laterally-coupled ridge-waveguide distributed feedback lasers fabricated without epitaxial regrowth steps have the advantages of process simplification and low cost. We present a laterally coupled grating with slots. The slots etched between the ridge and grating area are designed to suppress the lateral diffusion of carriers and to reduce the influence of the aspect-ratio-dependent-etching effect on the grating morphology in the etching process. Moreover, the grating height in this structure can be decreased to lower the aspect ratio significantly, which is advantageous over the conventional laterally coupled ridge waveguide gratings. The effects of five main structural parameters on the coupling characteristics of gratings are studied by MODE Solutions. It is found that varying the lateral width of the grating can be used as an effective way to tune the coupling strength; narrow slots (100 nm and 300 nm) and wide ridge (2 μm-4 μm) promote the stability of grating coupling coefficient and device performance. It is important to note that the grating bottom should be fabricated precisely. The comparative study of carrier distribution and mode field distribution shows that the introduction of narrow slots can strengthen the competitive advantage and stability of the fundamental mode. 相似文献
58.
《Arabian Journal of Chemistry》2022,15(7):103940
Fluoride anion (F?) affects environmental, biological, and chemical processes significantly. Therefore, its detection has received increasing attention, and sensitive, effective, and convenient probes for F? detection need to be developed urgently. In this work, two perylene tetra-(alkoxycarbonyl) (PTAC) based colorimetric and ratiometric probes, P1 and P2, were developed for the detection of F?. The interactions between F? and these two probes were investigated by absorption, electrochemistry, 1H NMR, and density functional methods. Both the two probes were complexed with F? with a ratio of 1:1. The detection limits of P1 and P2 were 0.22 μM and 0.87 μM, respectively. It was worth noting that the absorption peak of P1 showed a 190 nm red shift when sensing F?, and P1 is the largest red shift value reported in F? probes based on PTAC derivatives. This phenomenon was resulted from the unique configuration and deprotonation of P1 that can promote the intramolecular charge transfer (ICT). This strategy provides an example for the development of other ion probes based on D-A type ICT mechanism. 相似文献
59.
Dev Raj Alok Kumar Rohit Kumar Singh Abhishek Singh Bhadouria A.S.K. Sinha Deepak Dwivedi 《Current Opinion in Electrochemistry》2022
As the application of electrocatalyst continues to expand, envisaging the hidden mechanisms occurring at various length scale affecting the catalytic efficiency became important. To enhance the stability of electrocatalyst and reduce the cost, it is of paramount importance to reveal the active site's dynamics (using in situ techniques for getting the real-time information) which directly affect the reactions such as oxygen evolution reaction, hydrogen evolution reaction, and so on. Since such reactions are crucial for many engineering and scientific applications, in situ characterization techniques are required, which could capture such reactions happening at a different length and time scale. This article analyzes the recent progress made in the field of electrocatalyst's characterization using in situ neutron techniques. The article also paves the future path and has delineated the future challenges involved in multiscale correlative techniques (e.g., neutron techniques in the combination of synchrotron or microscopic techniques) used for getting the multiscale (atomic to micrometer range) mechanistic information about the electrocatalyst's working and degradation. 相似文献
60.
《Journal of Saudi Chemical Society》2022,26(4):101490
Biomass syngas is a form of renewable energy with very broad application prospects, and it has different combustion characteristics according to the fuel composition and processing technology of biomass syngas. The influence of combustion composition, diluent and temperature variation on combustion characteristics were studied in this paper. The FFCM-1 mechanism was used to investigate the combustion characteristics of CO/CH4/H2 under varied diluents CO2/N2 and temperature by using spherical expansion flame method and ANSYS CHEMKIN-PRO. The experimental laminar burning velocity was compared with the simulation results of FFCM-1 mechanism. The results reveal that the experimental data are in good agreement with the simulation results, which are somewhat different under the condition of rich fuel. The laminar burning velocity decreases significantly with the increase of diluent CO2/N2, with the effect of diluent CO2 being more significant. The laminar burning velocity increase dramatically with the increase of initial temperature, and the adiabatic flame temperature also decreases with the increase of diluent. The reduction caused by diluent CO2 is much larger than that caused by diluent N2. The change of initial temperature also affects the adiabatic flame temperature, but the range of variation is not as pronounced as that of diluent. Not only was the interaction between the combustion characteristics of CO/CH4/H2 under different diluents and temperature changes explored in this paper, but the influence mechanism was also revealed in depth. 相似文献